Research Data Leeds Repository

Data to Support a Study of Exploring the Influence of Counterions on a Hysteretic Spin-Transition in Isomorphous Iron(II) Complex Salts

Citation

Roberts, Thomas D. and Pask, Christopher M. and Capel Berdiell, Izar and Tuna, Floriana and Halcrow, Malcolm A. (2022) Data to Support a Study of Exploring the Influence of Counterions on a Hysteretic Spin-Transition in Isomorphous Iron(II) Complex Salts. University of Leeds. [Dataset] https://doi.org/10.5518/1233¹

Dataset description

The hysteretic spin transition shown by [FeL2][BF4]2 is quenched in its isomorphous perchlorate salt, which reflects more sluggish lattice dynamics in the presence of the larger ClO4 ion.

Keywords:	iron; zinc; N-donor ligands; spin-crossover; crystal engineering
Divisions:	Faculty of Engineering and Physical Sciences > School of Chemistry2
Related resources:	Location Type https://doi.org/10.1039/D2TC03654A3 Publication https://eprints.whiterose.ac.uk/191954/4 Publication
License:	Creative Commons Attribution 4.0 International (CC BY 4.0)
Date deposited:	11 Oct 2022 14:03
URI:	https://archive.researchdata.leeds.ac.uk/id/eprint/10325
Additional details Additional details Creators or authors: Creators ORCID Other ID Email Primary affiliation Primary affiliation ID Primary affiliation ID type Secondary affiliation Secondary affiliation ID Secondary affiliation ID type Roberts, Thomas D. University of Leeds https://ror.org/024mrxd33 ror Pask, Christopher M. https://orcid.org/0000-0002-2241-50696 University of Leeds https://ror.org/024mrxd33 ror Capel Berdiell, Izar https://orcid.org/0000-0003-3828-70977 University of Oslo https://ror.org/01xtthb56 ror Tuna, Floriana https://orcid.org/0000-0002-5541-17508 University of Manchester https://ror.org/027m9bs27 ror Halcrow, Malcolm A. https://orcid.org/0000-0001-7491-90349 University of Leeds https://ror.org/024mrxd33 ror Type of data: Dataset Research funders: EPSRC, Research Council of Norway, University of Leeds Publication date: 2022 Resource language: English Metadata language: English Publisher: University of Leeds Contact email: m.a.halcrow@leeds.ac.uk10 Last Modified: 02 Sep 2024 10:28

Files

Documentation

compound naming and metadata [132kB] 11 compound naming and metadata [132kB] 12 compound naming and metadata [132kB] 13 Security: Anyone File name: readme.pdf14 Content type: Documentation Mime-Type: application/pdf License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 132kB

Data

Elemental microanayses [108kB] 15 Elemental microanayses [108kB] 16 Elemental microanayses [108kB] 17 Security: Anyone File name: microanalysis.zip18 Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 108kB

Single crystal X-ray diffraction [6MB] 19 Single crystal X-ray diffraction [6MB] 20 Single crystal X-ray diffraction [6MB] 21 Security: Anyone File name: crystal.zip22 Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 6MB

X-ray powder diffraction [448kB] 23 X-ray powder diffraction [448kB] 24 X-ray powder diffraction [448kB] 25 Security: Anyone File name: XRPD.zip26 Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 448kB

Magnetic susceptibility measurements [316kB] 27 Magnetic susceptibility measurements [316kB] 28 Magnetic susceptibility measurements [316kB] 29 Security: Anyone File name: SQUID.zip30 Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 316kB

Thermogravimetric analyses [138kB] 31 Thermogravimetric analyses [138kB] 32 Thermogravimetric analyses [138kB] 33 Security: Anyone File name: TGA.zip34 Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 138kB

Differential scanning calorimetry [364kB] 35 Differential scanning calorimetry [364kB] 36 Differential scanning calorimetry [364kB] 37 Security: Anyone File name: DSC.zip38 Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 364kB

• 1. https://doi.org/10.5518/1233
• 2. https://archive.researchdata.leeds.ac.uk/view/divisions/CHEM/
• 3. https://doi.org/10.1039/D2TC03654A
• 4. https://eprints.whiterose.ac.uk/191954/
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• 6. https://orcid.org/0000-0002-2241-5069
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• 8. https://orcid.org/0000-0002-5541-1750
• 9. https://orcid.org/0000-0001-7491-9034
• 10. mailto:m.a.halcrow@leeds.ac.uk
• 11. https://archive.researchdata.leeds.ac.uk/1032/1/readme.pdf
• 12. https://archive.researchdata.leeds.ac.uk/1032/1/readme.pdf
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• 20. https://archive.researchdata.leeds.ac.uk/1032/3/crystal.zip
• 21. https://archive.researchdata.leeds.ac.uk/1032/3/crystal.zip
• 22. https://archive.researchdata.leeds.ac.uk/1032/3/crystal.zip
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• 26. https://archive.researchdata.leeds.ac.uk/1032/4/XRPD.zip
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• 29. https://archive.researchdata.leeds.ac.uk/1032/5/SQUID.zip
• 30. https://archive.researchdata.leeds.ac.uk/1032/5/SQUID.zip
• 31. https://archive.researchdata.leeds.ac.uk/1032/6/TGA.zip
• 32. https://archive.researchdata.leeds.ac.uk/1032/6/TGA.zip
• 33. https://archive.researchdata.leeds.ac.uk/1032/6/TGA.zip
• 34. https://archive.researchdata.leeds.ac.uk/1032/6/TGA.zip
• 35. https://archive.researchdata.leeds.ac.uk/1032/7/DSC.zip
• 36. https://archive.researchdata.leeds.ac.uk/1032/7/DSC.zip
• 37. https://archive.researchdata.leeds.ac.uk/1032/7/DSC.zip
• 38. https://archive.researchdata.leeds.ac.uk/1032/7/DSC.zip