Research Data Leeds Repository

Citation

Roberts, Thomas D., Pask, Christopher M., Capel Berdiell, Izar, Tuna, Floriana and Halcrow, Malcolm A. (2022) Data to Support a Study of Exploring the Influence of Counterions on a Hysteretic Spin-Transition in Isomorphous Iron(II) Complex Salts. University of Leeds. [Dataset] https://doi.org/10.5518/1233

Dataset description

The hysteretic spin transition shown by [FeL2][BF4]2 is quenched in its isomorphous perchlorate salt, which reflects more sluggish lattice dynamics in the presence of the larger ClO4 ion.

Keywords:	iron; zinc; N-donor ligands; spin-crossover; crystal engineering
Subjects:	F000 - Physical sciences > F100 - Chemistry > F130 - Structural chemistry > F131 - Crystallography F000 - Physical sciences > F200 - Materials science
Divisions:	Faculty of Engineering and Physical Sciences > School of Chemistry
Related resources:	Location Type https://doi.org/10.1039/D2TC03654A Publication https://eprints.whiterose.ac.uk/191954/ Publication
License:	Creative Commons Attribution 4.0 International (CC BY 4.0)
Date deposited:	11 Oct 2022 14:03
URI:	https://archive.researchdata.leeds.ac.uk/id/eprint/1032
Additional details Additional details Creators or authors: Creators ORCID Other ID Email Primary affiliation Primary affiliation ID Primary affiliation ID type Secondary affiliation Secondary affiliation ID Secondary affiliation ID type Roberts, Thomas D. University of Leeds https://ror.org/024mrxd33 ror Pask, Christopher M. https://orcid.org/0000-0002-2241-5069 University of Leeds https://ror.org/024mrxd33 ror Capel Berdiell, Izar https://orcid.org/0000-0003-3828-7097 University of Oslo https://ror.org/01xtthb56 ror Tuna, Floriana https://orcid.org/0000-0002-5541-1750 University of Manchester https://ror.org/027m9bs27 ror Halcrow, Malcolm A. https://orcid.org/0000-0001-7491-9034 University of Leeds https://ror.org/024mrxd33 ror Type of data: Dataset Research funders: EPSRC, Research Council of Norway, University of Leeds Publication date: 2022 Resource language: English Metadata language: English Publisher: University of Leeds Contact email: m.a.halcrow@leeds.ac.uk Last Modified: 08 Dec 2025 14:16

Files

Documentation

compound naming and metadata [132kB] compound naming and metadata [132kB] compound naming and metadata [132kB] Security: Anyone File name: readme.pdf Content type: Documentation Mime-Type: application/pdf License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 132kB

Data

Elemental microanayses [108kB] Elemental microanayses [108kB] Elemental microanayses [108kB] Security: Anyone File name: microanalysis.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 108kB

Single crystal X-ray diffraction [6MB] Single crystal X-ray diffraction [6MB] Single crystal X-ray diffraction [6MB] Security: Anyone File name: crystal.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 6MB

X-ray powder diffraction [448kB] X-ray powder diffraction [448kB] X-ray powder diffraction [448kB] Security: Anyone File name: XRPD.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 448kB

Magnetic susceptibility measurements [316kB] Magnetic susceptibility measurements [316kB] Magnetic susceptibility measurements [316kB] Security: Anyone File name: SQUID.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 316kB

Thermogravimetric analyses [138kB] Thermogravimetric analyses [138kB] Thermogravimetric analyses [138kB] Security: Anyone File name: TGA.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 138kB

Differential scanning calorimetry [364kB] Differential scanning calorimetry [364kB] Differential scanning calorimetry [364kB] Security: Anyone File name: DSC.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 364kB