Research Data Leeds Repository

Data to support study of the speciation of homochiral and heterochiral diastereomers of homoleptic cobalt(II) and zinc(II) PyBox complexes

Citation

Halcrow, Malcolm A. and Burrows, Kay E. and Kulmaczewski, Rafał and Cespedes, Oscar and Barrett, Simon A. (2018) Data to support study of the speciation of homochiral and heterochiral diastereomers of homoleptic cobalt(II) and zinc(II) PyBox complexes. University of Leeds. [Dataset] https://doi.org/10.5518/370¹

Dataset description

Heterochiral [M((R)-LiPr)((S)-LiPr)]2+ (M = Zn or Co) partially racemises by ligand redistribution in CD3CN, whereas [M((R)-LPh)((S)-LPh)]2+ does not.

Keywords:

cobalt; zinc; isomers; chirality

Subjects:

F000 - Physical sciences > F100 - Chemistry²

Divisions:

Faculty of Engineering and Physical Sciences > School of Chemistry³

Related resources:

Location	Type
https://doi.org/10.1016/j.poly.2018.04.030⁴	Publication
https://eprints.whiterose.ac.uk/130458/⁵	Publication

License:

Creative Commons Attribution 4.0 International (CC BY 4.0)

Date deposited:

18 May 2018 07:07

URI:

https://archive.researchdata.leeds.ac.uk/id/eprint/356⁶

Additional details

Creators or authors:

Creators	ORCID	Other ID	Email	Primary affiliation	Primary affiliation ID	Primary affiliation ID type	Secondary affiliation	Secondary affiliation ID	Secondary affiliation ID type
Halcrow, Malcolm A.	https://orcid.org/0000-0001-7491-9034⁷			University of Leeds	https://ror.org/024mrxd33	ror
Burrows, Kay E.	https://orcid.org/0000-0002-5485-6256⁸			University of Leeds	https://ror.org/024mrxd33	ror
Kulmaczewski, Rafał	https://orcid.org/0000-0002-3855-4530⁹			University of Leeds	https://ror.org/024mrxd33	ror
Cespedes, Oscar	https://orcid.org/0000-0002-5249-9523¹⁰			University of Leeds	https://ror.org/024mrxd33	ror
Barrett, Simon A.				University of Leeds	https://ror.org/024mrxd33	ror

Type of data:

Dataset

Research funders:

EPSRC, Leverhulme Trust

Grant numbers:

EP/K012568/1, RPG-2015-095, EP/K012568/1, EP/K00512X/1

Publication date:

2018

Resource language:

English

Metadata language:

English

Research project title:

Switchable molecular crystals, Exploiting a spin-crossover module, Switchable molecular crystals, SQUID magnetometer

Publisher:

University of Leeds

Contact email:

m.a.halcrow@leeds.ac.uk¹¹

Last Modified:

07 Aug 2024 13:20

Files

Documentation

Compound naming and metadata [661kB]

download/view file

¹²

Compound naming and metadata [661kB]

download/view file

¹⁴

List of files [19kB]

download/view file

¹⁶

List of files [19kB]

download/view file

¹⁸

Data

CHN microanalysis [2MB]

download/view file

²⁰

CHN microanalysis [2MB]

download/view file

²²

Single crystal X-ray diffraction [3MB]

download/view file

²⁴

Single crystal X-ray diffraction [3MB]

download/view file

²⁶

Magnetic susceptibility [355kB]

download/view file

²⁸

Magnetic susceptibility [355kB]

download/view file

³⁰

NMR spectra [74MB]

download/view file

³²

NMR spectra [74MB]

download/view file

³⁴

Evans method [54kB]

download/view file

³⁶

Evans method [54kB]

download/view file

³⁸

1. https://doi.org/10.5518/370
2. https://archive.researchdata.leeds.ac.uk/view/subjects/F100.html
3. https://archive.researchdata.leeds.ac.uk/view/divisions/CHEM/
4. https://doi.org/10.1016/j.poly.2018.04.030
5. https://eprints.whiterose.ac.uk/130458/
6. https://archive.researchdata.leeds.ac.uk/id/eprint/356
7. https://orcid.org/0000-0001-7491-9034
8. https://orcid.org/0000-0002-5485-6256
9. https://orcid.org/0000-0002-3855-4530
10. https://orcid.org/0000-0002-5249-9523
11. mailto:m.a.halcrow@leeds.ac.uk
12. https://archive.researchdata.leeds.ac.uk/356/1/readme.pdf
13. https://archive.researchdata.leeds.ac.uk/356/1/readme.pdf
14. https://archive.researchdata.leeds.ac.uk/356/1/readme.pdf
15. https://archive.researchdata.leeds.ac.uk/356/1/readme.pdf
16. https://archive.researchdata.leeds.ac.uk/356/7/files.txt
17. https://archive.researchdata.leeds.ac.uk/356/7/files.txt
18. https://archive.researchdata.leeds.ac.uk/356/7/files.txt
19. https://archive.researchdata.leeds.ac.uk/356/7/files.txt
20. https://archive.researchdata.leeds.ac.uk/356/2/Microanalysis.pdf
21. https://archive.researchdata.leeds.ac.uk/356/2/Microanalysis.pdf
22. https://archive.researchdata.leeds.ac.uk/356/2/Microanalysis.pdf
23. https://archive.researchdata.leeds.ac.uk/356/2/Microanalysis.pdf
24. https://archive.researchdata.leeds.ac.uk/356/3/crystal.zip
25. https://archive.researchdata.leeds.ac.uk/356/3/crystal.zip
26. https://archive.researchdata.leeds.ac.uk/356/3/crystal.zip
27. https://archive.researchdata.leeds.ac.uk/356/3/crystal.zip
28. https://archive.researchdata.leeds.ac.uk/356/4/magnetism.zip
29. https://archive.researchdata.leeds.ac.uk/356/4/magnetism.zip
30. https://archive.researchdata.leeds.ac.uk/356/4/magnetism.zip
31. https://archive.researchdata.leeds.ac.uk/356/4/magnetism.zip
32. https://archive.researchdata.leeds.ac.uk/356/5/NMR.zip
33. https://archive.researchdata.leeds.ac.uk/356/5/NMR.zip
34. https://archive.researchdata.leeds.ac.uk/356/5/NMR.zip
35. https://archive.researchdata.leeds.ac.uk/356/5/NMR.zip
36. https://archive.researchdata.leeds.ac.uk/356/6/Evans.zip
37. https://archive.researchdata.leeds.ac.uk/356/6/Evans.zip
38. https://archive.researchdata.leeds.ac.uk/356/6/Evans.zip
39. https://archive.researchdata.leeds.ac.uk/356/6/Evans.zip

Research Data Leeds Repository is powered by EPrints
Copyright © University of Leeds