Research Data Leeds Repository

Citation

Sun, Chao, Pham, Sang, Boyall, Sarah L., Douglas, Ben, Britton, Andrew J., Micklethwaite, Stuart, Chamberlain, Thomas W., Besenhard, Maximilian O., Brydson, Rik, Wu, Ke-Jun and Collins, Sean M. (2025) Characterisation data for 'Ultrasound-assisted continuous aqueous synthesis of sulfonate, imidazolate, and carboxylate MOFs with high space time yield'. University of Leeds. [Dataset] https://doi.org/10.5518/1609

Dataset description

Metal–organic frameworks exhibit promising properties for applications from gas separations to energy applications. Yet scale-up with non-toxic solvents remains a challenge. Combining the increased heat and mass transfer of flow reactors with the enhanced mixing and nucleation rates of sono-chemical synthesis, we developed an ultrasound-assisted two-phase flow platform for the aqueous synthesis of MOFs spanning three ligand chemistries, sulfonate Ca-NDS (water), imidazolate ZIF-8, and carboxylate UiO-66-NH2. This dataset includes the characterisation data supporting these results, highlighting the potential of ultrasound-assisted flow synthesis for MOFs.

Keywords:	metal-organic frameworks, flow chemistry, materials characterisation
Subjects:	F000 - Physical sciences > F200 - Materials science
Divisions:	Faculty of Engineering and Physical Sciences > School of Chemical and Process Engineering
Related resources:	Location Type https://doi.org/10.1038/s42004-025-01548-5 Publication https://eprints.whiterose.ac.uk/id/eprint/226449/ Publication
License:	Creative Commons Attribution 4.0 International (CC BY 4.0)
Date deposited:	15 May 2025 13:54
URI:	https://archive.researchdata.leeds.ac.uk/id/eprint/1410
Additional details Additional details Creators or authors: Creators ORCID Other ID Email Primary affiliation Primary affiliation ID Primary affiliation ID type Secondary affiliation Secondary affiliation ID Secondary affiliation ID type Sun, Chao https://orcid.org/0000-0001-7307-5685 University of Leeds https://ror.org/024mrxd33 ror Pham, Sang https://orcid.org/0000-0002-7347-4317 University of Leeds https://ror.org/024mrxd33 ror Boyall, Sarah L. https://orcid.org/0000-0001-5049-8335 University of Leeds https://ror.org/024mrxd33 ror Douglas, Ben https://orcid.org/0009-0002-9096-1325 University of Leeds https://ror.org/024mrxd33 ror Britton, Andrew J. https://orcid.org/0000-0003-4712-3414 University of Leeds https://ror.org/024mrxd33 ror Micklethwaite, Stuart https://orcid.org/0000-0001-7335-2785 University of Leeds https://ror.org/024mrxd33 ror Chamberlain, Thomas W. https://orcid.org/0000-0001-8100-6452 University of Leeds https://ror.org/024mrxd33 ror Besenhard, Maximilian O. https://orcid.org/0000-0002-5079-617X University College London https://ror.org/02jx3x895 ror Brydson, Rik https://orcid.org/0000-0003-2003-7612 University of Leeds https://ror.org/024mrxd33 ror Wu, Ke-Jun https://orcid.org/0000-0001-8658-5449 University of Leeds https://ror.org/024mrxd33 ror Zhejiang University https://ror.org/00a2xv884 ror Collins, Sean M. https://orcid.org/0000-0002-5151-6360 University of Leeds https://ror.org/024mrxd33 ror Type of data: Dataset Research funders: Royal Society, UK Research and Innovation, Engineering and Physical Sciences Research Council Grant numbers: RGS\R2\212076, EP/Y024583/1, EP/V028855/1 Publication date: 2025 Resource language: English Metadata language: English Publisher: University of Leeds Contact email: s.m.collins@leeds.ac.uk Last Modified: 05 Jun 2025 15:44

Files

Documentation

README_Collins_2025.txt [7kB] README_Collins_2025.txt [7kB] README_Collins_2025.txt [7kB] Security: Anyone File name: README_Collins_2025.txt Content type: Documentation Mime-Type: text/plain License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 7kB

Data

BET data [93kB] BET data [93kB] BET data [93kB] Security: Anyone File name: BET.zip Content type: Data Description: Gas sorption data on Ca-NDS (water), ZIF-8, and UiO-66-NH2 Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 93kB

FTIR data [33kB] FTIR data [33kB] FTIR data [33kB] Security: Anyone File name: FTIR.zip Content type: Data Description: FTIR spectroscopy data on Ca-NDS (water), ZIF-8, and UiO-66-NH2 Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 33kB

TGA data [104kB] TGA data [104kB] TGA data [104kB] Security: Anyone File name: TGA.zip Content type: Data Description: Thermogravimetric data on Ca-NDS (water), ZIF-8, and UiO-66-NH2 Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 104kB

XPS data [120kB] XPS data [120kB] XPS data [120kB] Security: Anyone File name: XPS.zip Content type: Data Description: X-ray photoelectron spectroscopy on Ca-NDS (water), ZIF-8, and UiO-66-NH2 Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 120kB

XRD data [236kB] XRD data [236kB] XRD data [236kB] Security: Anyone File name: XRD.zip Content type: Data Description: X-ray diffraction data on Ca-NDS (water), ZIF-8, and UiO-66-NH2 Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 236kB

Ultrasound power and space time yield [467B] Ultrasound power and space time yield [467B] Ultrasound power and space time yield [467B] Security: Anyone File name: UltrasoundPower_Effect_STY.csv Content type: Data Description: Dependence of space time yield on ultrasound power for synthesized Ca-NDS (water), ZIF-8, and UiO-66-NH2 Mime-Type: text/csv License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 467B

Cryo-SEM-EDS data [3MB] Cryo-SEM-EDS data [3MB] Cryo-SEM-EDS data [3MB] Security: Anyone File name: CryoSEM-EDS.zip Content type: Data Description: Elemental mapping of Ca-NDS (water) polymer membranes by cryogenic scanning electron microscopy X-ray energy dispersive spectroscopy Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 3MB

SEM and SEM-EDS data [68MB] SEM and SEM-EDS data [68MB] SEM and SEM-EDS data [68MB] Security: Anyone File name: SEM_and_SEM-EDS.zip Content type: Data Description: Scanning electron microscopy and elemental mapping of Ca-NDS (water), ZIF-8, and UiO-66-NH2 Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 68MB

EIS data [3kB] EIS data [3kB] EIS data [3kB] Security: Anyone File name: EIS.zip Content type: Data Description: Electrochemical impedance spectroscopy of pellets and membranes of Ca-NDS (water) Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 3kB

Light Microscopy data [481kB] Light Microscopy data [481kB] Light Microscopy data [481kB] Security: Anyone File name: LightMicroscopy.zip Content type: Data Description: Light micgrographs of Ca-NDS (water) Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 481kB