Research Data Leeds Repository

Data to support study of the speciation of homochiral and heterochiral diastereomers of homoleptic cobalt(II) and zinc(II) PyBox complexes

Halcrow, Malcolm A and Burrows, Kay E and Kulmaczewski, Rafał and Cespedes, Oscar and Barrett, Simon A (2018) Data to support study of the speciation of homochiral and heterochiral diastereomers of homoleptic cobalt(II) and zinc(II) PyBox complexes. University of Leeds. [Dataset] https://doi.org/10.5518/370

Dataset description

Heterochiral [M((R)-LiPr)((S)-LiPr)]2+ (M = Zn or Co) partially racemises by ligand redistribution in CD3CN, whereas [M((R)-LPh)((S)-LPh)]2+ does not.

Keywords:	cobalt; zinc; isomers; chirality
Subjects:	F000 - Physical sciences > F100 - Chemistry
Divisions:	Faculty of Mathematics and Physical Sciences > School of Chemistry
Related resources:	Location Type https://doi.org/10.1016/j.poly.2018.04.030 Publication http://eprints.whiterose.ac.uk/130458/ Publication
License:	Creative Commons Attribution 4.0 International (CC BY 4.0)
Date deposited:	18 May 2018 07:07
URI:	http://archive.researchdata.leeds.ac.uk/id/eprint/356
Additional details Additional details Creators: Creators ORCID Other ID Email Primary affiliation Primary affiliation ID Primary affiliation ID type Secondary affiliation Secondary affiliation ID Secondary affiliation ID type Halcrow, Malcolm A https://orcid.org/0000-0001-7491-9034 University of Leeds https://doi.org/10.13039/501100000777 crossref Burrows, Kay E https://orcid.org/0000-0002-5485-6256 University of Leeds https://doi.org/10.13039/501100000777 crossref Kulmaczewski, Rafał https://orcid.org/0000-0002-3855-4530 University of Leeds https://doi.org/10.13039/501100000777 crossref Cespedes, Oscar https://orcid.org/0000-0002-5249-9523 University of Leeds https://doi.org/10.13039/501100000777 crossref Barrett, Simon A University of Leeds https://doi.org/10.13039/501100000777 crossref Type of data: Dataset Research funders: EPSRC, Leverhulme Trust Grant numbers: EP/K012568/1, RPG-2015-095, EP/K012568/1, EP/K00512X/1 Publication date: 2018 Resource language: English Metadata language: English Research project title: Switchable molecular crystals, Exploiting a spin-crossover module, Switchable molecular crystals, SQUID magnetometer Publisher: University of Leeds Contact Email Address: m.a.halcrow@leeds.ac.uk Last Modified: 18 May 2018 22:45

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Documentation

Compound naming and metadata [661kB] Compound naming and metadata [661kB] Compound naming and metadata [661kB] Visible to: Anyone File name: readme.pdf Content type: Documentation Mime-Type: application/pdf License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 661kB

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Data

CHN microanalysis [2MB] CHN microanalysis [2MB] CHN microanalysis [2MB] Visible to: Anyone File name: Microanalysis.pdf Content type: Data Mime-Type: application/pdf License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 2MB

Single crystal X-ray diffraction [3MB] Single crystal X-ray diffraction [3MB] Single crystal X-ray diffraction [3MB] Visible to: Anyone File name: crystal.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 3MB

Magnetic susceptibility [355kB] Magnetic susceptibility [355kB] Magnetic susceptibility [355kB] Visible to: Anyone File name: magnetism.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 355kB

NMR spectra [74MB] NMR spectra [74MB] NMR spectra [74MB] Visible to: Anyone File name: NMR.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 74MB

Evans method [54kB] Evans method [54kB] Evans method [54kB] Visible to: Anyone File name: Evans.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 54kB