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Data to support study of the speciation of homochiral and heterochiral diastereomers of homoleptic cobalt(II) and zinc(II) PyBox complexes

Halcrow, Malcolm A and Burrows, Kay E and Kulmaczewski, Rafał and Cespedes, Oscar and Barrett, Simon A (2018) Data to support study of the speciation of homochiral and heterochiral diastereomers of homoleptic cobalt(II) and zinc(II) PyBox complexes. University of Leeds. [Dataset] https://doi.org/10.5518/370

Dataset description

Heterochiral [M((R)-LiPr)((S)-LiPr)]2+ (M = Zn or Co) partially racemises by ligand redistribution in CD3CN, whereas [M((R)-LPh)((S)-LPh)]2+ does not.

Keywords: cobalt; zinc; isomers; chirality
Subjects: F000 - Physical sciences > F100 - Chemistry
Divisions: Faculty of Mathematics and Physical Sciences > School of Chemistry
Related resources:
LocationType
https://doi.org/10.1016/j.poly.2018.04.030Publication
http://eprints.whiterose.ac.uk/130458/Publication
License: Creative Commons Attribution 4.0 International (CC BY 4.0)
Date deposited: 18 May 2018 07:07
URI: https://archive.researchdata.leeds.ac.uk/id/eprint/356

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