Research Data Leeds Repository

Citation

Halcrow, Malcolm A. and Burrows, Kay E. and Kulmaczewski, Rafał and Cespedes, Oscar and Barrett, Simon A. (2018) Data to support study of the speciation of homochiral and heterochiral diastereomers of homoleptic cobalt(II) and zinc(II) PyBox complexes. University of Leeds. [Dataset] https://doi.org/10.5518/370

Dataset description

Heterochiral [M((R)-LiPr)((S)-LiPr)]2+ (M = Zn or Co) partially racemises by ligand redistribution in CD3CN, whereas [M((R)-LPh)((S)-LPh)]2+ does not.

Keywords:	cobalt; zinc; isomers; chirality
Subjects:	F000 - Physical sciences > F100 - Chemistry
Divisions:	Faculty of Engineering and Physical Sciences > School of Chemistry
Related resources:	Location Type https://doi.org/10.1016/j.poly.2018.04.030 Publication https://eprints.whiterose.ac.uk/130458/ Publication
License:	Creative Commons Attribution 4.0 International (CC BY 4.0)
Date deposited:	18 May 2018 07:07
URI:	https://archive.researchdata.leeds.ac.uk/id/eprint/356
Additional details Additional details Creators or authors: Creators ORCID Other ID Email Primary affiliation Primary affiliation ID Primary affiliation ID type Secondary affiliation Secondary affiliation ID Secondary affiliation ID type Halcrow, Malcolm A. https://orcid.org/0000-0001-7491-9034 University of Leeds https://ror.org/024mrxd33 ror Burrows, Kay E. https://orcid.org/0000-0002-5485-6256 University of Leeds https://ror.org/024mrxd33 ror Kulmaczewski, Rafał https://orcid.org/0000-0002-3855-4530 University of Leeds https://ror.org/024mrxd33 ror Cespedes, Oscar https://orcid.org/0000-0002-5249-9523 University of Leeds https://ror.org/024mrxd33 ror Barrett, Simon A. University of Leeds https://ror.org/024mrxd33 ror Type of data: Dataset Research funders: EPSRC, Leverhulme Trust Grant numbers: EP/K012568/1, RPG-2015-095, EP/K012568/1, EP/K00512X/1 Publication date: 2018 Resource language: English Metadata language: English Research project title: Switchable molecular crystals, Exploiting a spin-crossover module, Switchable molecular crystals, SQUID magnetometer Publisher: University of Leeds Contact email: m.a.halcrow@leeds.ac.uk Last Modified: 07 Aug 2024 13:20

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Documentation

Compound naming and metadata [661kB] Compound naming and metadata [661kB] Compound naming and metadata [661kB] Security: Anyone File name: readme.pdf Content type: Documentation Mime-Type: application/pdf License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 661kB

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Data

CHN microanalysis [2MB] CHN microanalysis [2MB] CHN microanalysis [2MB] Security: Anyone File name: Microanalysis.pdf Content type: Data Mime-Type: application/pdf License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 2MB

Single crystal X-ray diffraction [3MB] Single crystal X-ray diffraction [3MB] Single crystal X-ray diffraction [3MB] Security: Anyone File name: crystal.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 3MB

Magnetic susceptibility [355kB] Magnetic susceptibility [355kB] Magnetic susceptibility [355kB] Security: Anyone File name: magnetism.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 355kB

NMR spectra [74MB] NMR spectra [74MB] NMR spectra [74MB] Security: Anyone File name: NMR.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 74MB

Evans method [54kB] Evans method [54kB] Evans method [54kB] Security: Anyone File name: Evans.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 54kB