Research Data Leeds Repository

Data to support study of 2,6-Di(pyrazol-1-yl)pyridine-4-carboxylate Esters with Alkyl Chain Substituents, and their Iron(II) Complexes

Halcrow, Malcolm A and Galadzhun, Iurii and Kulmaczewski, Rafał and Cespedes, Oscar and Yamada, Mihoko and Yoshinari, Nobuto and Konno, Takumi (2018) Data to support study of 2,6-Di(pyrazol-1-yl)pyridine-4-carboxylate Esters with Alkyl Chain Substituents, and their Iron(II) Complexes. University of Leeds. [Dataset] https://doi.org/10.5518/455

Dataset description

Two series of the title compounds have been prepared. Solid materials with longer chain substituents transform into a predominantly high-spin form when heated to ca 170 °C, which may reflect conformational changes in the alkyl chains.

Keywords:	iron; spin-crossover; isomers; chirality
Subjects:	F000 - Physical sciences > F100 - Chemistry
Divisions:	Faculty of Mathematics and Physical Sciences > School of Chemistry
Related resources:	Location Type https://doi.org/10.1021/acs.inorgchem.8b02289 Publication http://eprints.whiterose.ac.uk/137202/ Publication
License:	Creative Commons Attribution 4.0 International (CC BY 4.0)
Date deposited:	18 Feb 2020 09:36
URI:	http://archive.researchdata.leeds.ac.uk/id/eprint/644
Additional details Additional details Creators: Creators ORCID Other ID Email Primary affiliation Primary affiliation ID Primary affiliation ID type Secondary affiliation Secondary affiliation ID Secondary affiliation ID type Halcrow, Malcolm A https://orcid.org/0000-0001-7491-9034 Galadzhun, Iurii https://orcid.org/0000-0002-0512-3830 Kulmaczewski, Rafał https://orcid.org/0000-0002-3855-4530 Cespedes, Oscar https://orcid.org/0000-0002-5249-9523 Yamada, Mihoko https://orcid.org/0000-0002-3789-6600 Yoshinari, Nobuto https://orcid.org/0000-0003-2457-0967 Konno, Takumi https://orcid.org/0000-0003-4612-5418 Type of data: Dataset Research funders: EPSRC, University of Leeds, EPSRC, EPSRC Grant numbers: EP/K012568/1, EP/K012568/1, EP/K00512X/1 Publication date: 2018 Resource language: English Metadata language: English Research project title: Switchable molecular crystals, LIRS scholarship, Switchable molecular crystals, SQUID magnetometer Publisher: University of Leeds Contact Email Address: m.a.halcrow@leeds.ac.uk Last Modified: 10 Jun 2020 17:10

Files

Documentation

compound naming and metadata [1MB] compound naming and metadata [1MB] compound naming and metadata [1MB] Visible to: Anyone File name: readme.pdf Content type: Documentation Mime-Type: application/pdf License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 1MB

Data

CHN microanalyses [5MB] CHN microanalyses [5MB] CHN microanalyses [5MB] Visible to: Anyone File name: Microanalysis.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 5MB

Single crystal X-ray diffraction [3MB] Single crystal X-ray diffraction [3MB] Single crystal X-ray diffraction [3MB] Visible to: Anyone File name: crystal.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 3MB

Magnetic susceptibility [2MB] Magnetic susceptibility [2MB] Magnetic susceptibility [2MB] Visible to: Anyone File name: magnetism.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 2MB

Evans method [12MB] Evans method [12MB] Evans method [12MB] Visible to: Anyone File name: Evans.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 12MB

NMR spectra [89MB] NMR spectra [89MB] NMR spectra [89MB] Visible to: Anyone File name: NMR.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 89MB

X-ray powder diffraction [1MB] X-ray powder diffraction [1MB] X-ray powder diffraction [1MB] Visible to: Anyone File name: XRPD.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 1MB

Thermogravimetric analyses [2MB] Thermogravimetric analyses [2MB] Thermogravimetric analyses [2MB] Visible to: Anyone File name: TGA.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 2MB

Differential Scanning Calorimetry [10MB] Differential Scanning Calorimetry [10MB] Differential Scanning Calorimetry [10MB] Visible to: Anyone File name: DSC.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 10MB