Research Data Leeds Repository
![[feed]](/style/images/feed-icon-14x14.png){kind=icon}
Data to support study of Elucidating the Structural Chemistry of a Hysteretic Iron(II) Spin-Crossover Compound From its Copper(II) and Zinc(II) Congeners
Halcrow, Malcolm A and Pask, Christopher M and Greatorex, Sam and Kulmaczewski, Rafał and Baldansuren, Amgalanbaatar and McInnes, Eric J L and Bamiduro, Faith and Yamada, Mihoko and Yoshinari, Nobuto (2020) Data to support study of Elucidating the Structural Chemistry of a Hysteretic Iron(II) Spin-Crossover Compound From its Copper(II) and Zinc(II) Congeners. University of Leeds. [Dataset] https://doi.org/10.5518/773
Dataset description
Structurally different [ML2][BF4]2∙2H2O (L = 2,6-bis[5-methyl-1H-pyrazol-3-yl]pyridine; M = Fe, Cu or Zn) form the same anhydrous phase upon annealing, which transforms to one of two new phases near room temperature.
| Keywords: | iron; copper; zinc; spin-crossover; X-ray diffraction; EPR spectroscopy | ||||||
|---|---|---|---|---|---|---|---|
| Subjects: | F000 - Physical sciences > F100 - Chemistry | ||||||
| Divisions: | Faculty of Engineering and Physical Sciences > School of Chemistry | ||||||
| Related resources: |
|
||||||
| License: | Creative Commons Attribution 4.0 International (CC BY 4.0) | ||||||
| Date deposited: | 07 Feb 2020 14:32 | ||||||
| URI: | http://archive.researchdata.leeds.ac.uk/id/eprint/640 | ||||||
Files
Documentation
compound naming and metadata [206kB]  |
compound naming and metadata [206kB] 
compound naming and metadata [206kB] Data
CHN microanalysis [2MB] |
Thermogravimetric analysis [796kB] |
Single crystal X-ray diffraction [6MB] |
Magnetic susceptibility [303kB] |
Differential scanning calorimetry [1MB] |
X-ray powder diffraction [5MB] |
EPR spectra [21MB] |