Research Data Leeds Repository

Data to support "Cyclotriveratrylene-tethered trinuclear palladium(II)-NHC com-plexes; reversal of site selectivity in Suzuki-Miyaura reactions"

Hardie, Michaele and Fowler, Jonathan and Britton, Edward and Pask, Christopher and Willans, Charlotte (2019) Data to support "Cyclotriveratrylene-tethered trinuclear palladium(II)-NHC com-plexes; reversal of site selectivity in Suzuki-Miyaura reactions". University of Leeds. [Dataset] https://doi.org/10.5518/716

Dataset description

Trinuclear complexes with three palladium N-heterocyclic carbene (NHC) centres tethered onto a host-type cyclotriguaiacylene scaffold, and monomeric analogues were studied by NMR, infrared spectroscopy, mass spectrometry and structures determined by X-ray crystallography. Use of the complexes to catalyse Suzuki Miyaura cross-coupling reactions was investigated.

Keywords:	cyclotriveratrylene, palladium, catalysis
Subjects:	F000 - Physical sciences > F100 - Chemistry
Divisions:	Faculty of Mathematics and Physical Sciences > School of Chemistry
Related resources:	Location Type http://doi.org/10.1039/C9DT03400E Publication http://eprints.whiterose.ac.uk/150915/ Publication
License:	Creative Commons Attribution 4.0 International (CC BY 4.0)
Date deposited:	18 Sep 2019 12:47
URI:	http://archive.researchdata.leeds.ac.uk/id/eprint/577
Additional details Additional details Creators: Creators ORCID Other ID Email Primary affiliation Primary affiliation ID Primary affiliation ID type Secondary affiliation Secondary affiliation ID Secondary affiliation ID type Hardie, Michaele https://orcid.org/0000-0001-6586-7981 University Of Leeds https://doi.org/10.13039/501100000777 crossref Fowler, Jonathan https://orcid.org/0000-0001-8142-9084 University Of Leeds https://doi.org/10.13039/501100000777 crossref Britton, Edward University Of Leeds https://doi.org/10.13039/501100000777 crossref Pask, Christopher https://orcid.org/0000-0002-2241-5069 University Of Leeds https://doi.org/10.13039/501100000777 crossref Willans, Charlotte https://orcid.org/0000-0003-0412-8821 University Of Leeds https://doi.org/10.13039/501100000777 crossref Type of data: Dataset Research funders: EPSRC, EPSRC, EPSRC, Diamond Light Source Grant numbers: EP/K039202/1, DTG-2014, DTG-2016, MT-15059 Publication date: 2019 Resource language: English Publisher: University of Leeds Contact Email Address: m.j.hardie@leeds.ac.uk Last Modified: 10 Jun 2020 17:12

Files

Documentation

compound naming and metadata [556kB] compound naming and metadata [556kB] compound naming and metadata [556kB] Visible to: Anyone File name: readme.pdf Content type: Documentation Mime-Type: application/pdf License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 556kB

Data

Crystal Structures [3MB] Crystal Structures [3MB] Crystal Structures [3MB] Visible to: Anyone File name: Crystal_Structures.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 3MB

Nuclear Magnetic Resonance [561MB] Nuclear Magnetic Resonance [561MB] Nuclear Magnetic Resonance [561MB] Visible to: Anyone File name: NMR.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 561MB

mass spectrometry [545kB] mass spectrometry [545kB] mass spectrometry [545kB] Visible to: Anyone File name: mass_spec.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 545kB

Infrared and CHN [1MB] Infrared and CHN [1MB] Infrared and CHN [1MB] Visible to: Anyone File name: Analysis.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 1MB