Research Data Leeds Repository

Data to support study of Iron(II) Complexes of 4-(Alkyldisulfanyl)-2,6-di(pyrazolyl)pyridine Derivatives. Correlation of Spin-Crossover Cooperativity with Molecular Structure Following Single-Crystal-to-Single-Crystal Desolvation

Halcrow, Malcolm A and Kulmaczewski, Rafał and Kershaw Cook, Laurence J and Pask, Christopher M. and Cespedes, Oscar (2022) Data to support study of Iron(II) Complexes of 4-(Alkyldisulfanyl)-2,6-di(pyrazolyl)pyridine Derivatives. Correlation of Spin-Crossover Cooperativity with Molecular Structure Following Single-Crystal-to-Single-Crystal Desolvation. University of Leeds. [Dataset] https://doi.org/10.5518/1098

Dataset description

[Fe(L1)2]X2 (1X2) form mixtures of solvated phases from acetone/diethyl ether, which transform to the same solvent-free material 1X2·sf upon mild heating. 1X2·sf exhibit abrupt spin-transitions with up to 38 K thermal hysteresis.

Keywords: iron; spin crossover; X-ray crystallography; single-crystal-to-single-crystal reactions; magnetic measurements
Subjects: F000 - Physical sciences > F100 - Chemistry
Divisions: Faculty of Mathematics and Physical Sciences > School of Chemistry
Related resources:
LocationType
https://doi.org/10.1021/acs.cgd.2c00005Publication
License: Creative Commons Attribution 4.0 International (CC BY 4.0)
Date deposited: 04 Feb 2022 14:28
URI: http://archive.researchdata.leeds.ac.uk/id/eprint/926

Files

Documentation

Data

Research Data Leeds Repository is powered by EPrints
Copyright © 2022 University of Leeds