Research Data Leeds Repository

Data to support study of Modulating the Magnetic Properties of Copper(II)/Nitroxyl Heterospin Complexes by Suppression of the Jahn-Teller Distortion

Citation

Halcrow, Malcolm A. and Greatorex, Sam and Fokin, Sergey V. and Kulmaczewski, Rafał and Cespedes, Oscar and Yamada, Mihoko and Yoshinari, Nobuto and Konno, Takumi and Sproules, Stephen and Ovcharenko, Victor I. (2020) Data to support study of Modulating the Magnetic Properties of Copper(II)/Nitroxyl Heterospin Complexes by Suppression of the Jahn-Teller Distortion. University of Leeds. [Dataset] https://doi.org/10.5518/591¹

This item is part of the Jahn Teller Effects in Heterospin Complexes² collection.

Dataset description

Ferromagnetic coupling between the Cu and L1 ligand radical spins in [Cu(L)L1][BF4]2 (L1 = 2,6-bis{1-oxyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-2-yl}pyridine) is enhanced by a sterically bulky ‘L’ co-ligand.

Keywords:

copper; nitroxyl; Jahn-Teller effect; magnetic properties

Subjects:

F000 - Physical sciences > F100 - Chemistry³

Divisions:

Faculty of Engineering and Physical Sciences > School of Chemistry⁴

Related resources:

Location	Type
https://doi.org/10.1021/acs.inorgchem.0c01345⁵	Publication
https://eprints.whiterose.ac.uk/161623/⁶	Publication

License:

Creative Commons Attribution 4.0 International (CC BY 4.0)

Date deposited:

09 Jun 2020 16:02

URI:

https://archive.researchdata.leeds.ac.uk/id/eprint/686⁷

Additional details

Creators or authors:

Creators	ORCID	Primary affiliation	Primary affiliation ID	Primary affiliation ID type
Halcrow, Malcolm A.	https://orcid.org/0000-0001-7491-9034⁸	University of Leeds	https://ror.org/024mrxd33	ror
Greatorex, Sam		University of Leeds	https://ror.org/024mrxd33	ror
Fokin, Sergey V.	https://orcid.org/0000-0002-1231-1282⁹	Russian Academy of Sciences	https://ror.org/05qrfxd25	ror
Kulmaczewski, Rafał	https://orcid.org/0000-0002-3855-4530¹⁰	University of Leeds	https://ror.org/024mrxd33	ror
Cespedes, Oscar	https://orcid.org/0000-0002-5249-9523¹¹	University of Leeds	https://ror.org/024mrxd33	ror
Yamada, Mihoko	https://orcid.org/0000-0002-3789-6600¹²	Nara Institute of Science and Technology	https://ror.org/05bhada84	ror
Yoshinari, Nobuto	https://orcid.org/0000-0003-2457-0967¹³	Osaka University	https://ror.org/035t8zc32	ror
Konno, Takumi	https://orcid.org/0000-0003-4612-5418¹⁴	Osaka University	https://ror.org/035t8zc32	ror
Sproules, Stephen	https://orcid.org/0000-0003-3587-0375¹⁵	University of Glasgow	https://ror.org/00vtgdb53	ror
Ovcharenko, Victor I.	https://orcid.org/0000-0002-8280-8112¹⁶	Russian Academy of Sciences	https://ror.org/05qrfxd25	ror

Type of data:

Dataset

Research funders:

Royal Society, EPSRC, EPSRC, EPSRC

Grant numbers:

IE150010, EP/M506552/1, EP/K012568/1, EP/K00512X/1

Publication date:

2020

Resource language:

English

Metadata language:

English

Research project title:

International exchange, DTP grant to Leeds School of Chemistry, Switchable molecular crystals, SQUID magnetometer

Publisher:

University of Leeds

Contact email:

m.a.halcrow@leeds.ac.uk¹⁷

Last Modified:

20 Dec 2024 14:26

Files

Documentation

compound naming and metadata [1MB]

¹⁸

compound naming and metadata [1MB]

²⁰

Data

CHN microanalyses [896kB]

²²