Research Data Leeds Repository

Data to support study of An Iron(II) Coordination Polymer of a Triazolyl Tris-Heterocycle Showing a Spin State Conversion Triggered by Loss of Lattice Solvent

Halcrow, Malcolm A and Galadzhun, Iurii and Capel Berdiell, Izar and Shahid, Namrah (2019) Data to support study of An Iron(II) Coordination Polymer of a Triazolyl Tris-Heterocycle Showing a Spin State Conversion Triggered by Loss of Lattice Solvent. University of Leeds. [Dataset] https://doi.org/10.5518/728

Dataset description

Solvated crystals of “[FeL2][BF4]2·H2O” (L = 2-(1,2,4-triazol-1-yl)-6-(pyrazol-1-yl)pyridine) contain a 1D coordination polymer. The crystals undergo a gradual spin-crossover on warming from 150 K, associated with loss of a lattice water molecule.

Keywords:	iron; coordination polymer; spin-crossover; X-ray crystallography; magnetic measurements
Subjects:	F000 - Physical sciences > F100 - Chemistry
Divisions:	Faculty of Mathematics and Physical Sciences > School of Chemistry
Related resources:	Location Type http://doi.org/10.1039/C9CE01496A Publication http://eprints.whiterose.ac.uk/152004/ Publication
License:	Creative Commons Attribution 4.0 International (CC BY 4.0)
Date deposited:	10 Oct 2019 14:10
URI:	http://archive.researchdata.leeds.ac.uk/id/eprint/583
Additional details Additional details Creators: Creators ORCID Other ID Email Primary affiliation Primary affiliation ID Primary affiliation ID type Secondary affiliation Secondary affiliation ID Secondary affiliation ID type Halcrow, Malcolm A https://orcid.org/0000-0001-7491-9034 University Of Leeds https://doi.org/10.13039/501100000777 crossref Galadzhun, Iurii https://orcid.org/0000-0002-0512-3830 University Of Leeds https://doi.org/10.13039/501100000777 Capel Berdiell, Izar https://orcid.org/0000-0003-3828-7097 University Of Leeds https://doi.org/10.13039/501100000777 Shahid, Namrah https://orcid.org/0000-0002-8090-7619 University Of Leeds https://doi.org/10.13039/501100000777 Type of data: Dataset Research funders: Leverhulme Trust, EPSRC, University of Leeds Grant numbers: RPG-2015-095, EP/N509681/1 Publication date: 2019 Resource language: English Research project title: Exploiting a spin-crossover module, DTP grant to Leeds School of Chemistry, LIDS scholarship to Iurii Galadzhun Publisher: University of Leeds Contact Email Address: m.a.halcrow@leeds.ac.uk Last Modified: 10 Jun 2020 17:12

Files

Documentation

readme.pdf [63kB] readme.pdf [63kB] readme.pdf [63kB] Visible to: Anyone File name: readme.pdf Content type: Documentation Mime-Type: application/pdf License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 63kB

Data

crystal.zip [2MB] crystal.zip [2MB] crystal.zip [2MB] Visible to: Anyone File name: crystal.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 2MB

microanalysis.zip [249kB] microanalysis.zip [249kB] microanalysis.zip [249kB] Visible to: Anyone File name: microanalysis.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 249kB

SQUID.zip [249kB] SQUID.zip [249kB] SQUID.zip [249kB] Visible to: Anyone File name: SQUID.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 249kB