Research Data Leeds Repository

Citation

Halcrow, Malcolm A. and Greatorex, Sam and Vincent, Kevin B. and Baldansuren, Amgalanbaatar and McInnes, Eric J. L. and Patmore, Nathan J. and Sproules, Stephen (2019) Data to support study of Rigidification of a Macrocyclic Tris-Catecholate Scaffold Leads to Electronic Localisation of its Mixed Valent Redox Product. University of Leeds. [Dataset] https://doi.org/10.5518/557

Dataset description

The mixed valent radical obtained by oxidation of the platinum complex of a new tris-catecholate macrocycle has a class I, electronically localised structure.

Keywords:	transition metals; dioxolene ligands; voltammetry; spectroelectrochemistry; EPR spectroscopy; DFT calculations
Subjects:	F000 - Physical sciences > F100 - Chemistry
Divisions:	Faculty of Engineering and Physical Sciences > School of Chemistry
Related resources:	Location Type https://doi.org/10.1039/C8CC10122A Publication https://eprints.whiterose.ac.uk/141857/ Publication
License:	Creative Commons Attribution 4.0 International (CC BY 4.0)
Date deposited:	27 Feb 2019 13:48
URI:	https://archive.researchdata.leeds.ac.uk/id/eprint/494
Additional details Additional details Creators or authors: Creators ORCID Other ID Email Primary affiliation Primary affiliation ID Primary affiliation ID type Secondary affiliation Secondary affiliation ID Secondary affiliation ID type Halcrow, Malcolm A. https://orcid.org/0000-0001-7491-9034 University of Leeds https://ror.org/024mrxd33 ror Greatorex, Sam University of Leeds https://ror.org/024mrxd33 ror Vincent, Kevin B. https://orcid.org/0000-0002-5803-0291 University of East Anglia https://ror.org/026k5mg93 ror Baldansuren, Amgalanbaatar https://orcid.org/0000-0001-8767-3731 University of Manchester https://ror.org/027m9bs27 ror McInnes, Eric J. L. https://orcid.org/0000-0002-4090-7040 University of Manchester https://ror.org/027m9bs27 ror Patmore, Nathan J. https://orcid.org/0000-0002-4910-966X University of Huddersfield https://ror.org/05t1h8f27 ror Sproules, Stephen https://orcid.org/0000-0003-3587-0375 University of Glasgow https://ror.org/00vtgdb53 ror Type of data: Dataset Research funders: EPSRC Grant numbers: EP/M506552/1 Publication date: 2019 Resource language: English Metadata language: English Research project title: DTP grant to Leeds School of Chemistry Publisher: University of Leeds Contact email: m.a.halcrow@leeds.ac.uk Last Modified: 17 Dec 2024 12:18

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Documentation

compound naming and metadata [126kB] compound naming and metadata [126kB] compound naming and metadata [126kB] Security: Anyone File name: readme.pdf Content type: Documentation Mime-Type: application/pdf License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 126kB

Data

CHN microanalysis [398kB] CHN microanalysis [398kB] CHN microanalysis [398kB] Security: Anyone File name: Microanalysis.pdf Content type: Data Mime-Type: application/pdf License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 398kB

NMR spectra [2MB] NMR spectra [2MB] NMR spectra [2MB] Security: Anyone File name: NMR.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 2MB

Mass spectra [75MB] Mass spectra [75MB] Mass spectra [75MB] Security: Anyone File name: ESMS.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 75MB

Single crystal X-ray diffraction [301kB] Single crystal X-ray diffraction [301kB] Single crystal X-ray diffraction [301kB] Security: Anyone File name: crystal.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 301kB

Voltammetry [53kB] Voltammetry [53kB] Voltammetry [53kB] Security: Anyone File name: voltammetry.zip Content type: Data Mime-Type: XRPD.zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 53kB

EPR spectra [271kB] EPR spectra [271kB] EPR spectra [271kB] Security: Anyone File name: EPR.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 271kB

UV/vis/NIR spectroelectrochemistry [29kB] UV/vis/NIR spectroelectrochemistry [29kB] UV/vis/NIR spectroelectrochemistry [29kB] Security: Anyone File name: spectroelectrochemistry.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 29kB