This dataset contains experimental data presented in the paper titled 'Rapid Preparation of Highly Reliable PDMS Double Emulsion Microfluidic Devices' supplementary.docx contains the useful information mentioned in the manuscript. plasma_cleaner.jpg is the equipment used for coating and bonding. pumps_and_microscope.jpg is the set-up for running microfluidic devices and recording movies. Movie1.mp4 and Movie2.mp4 are the Movies of W/O/W generation by conventional PDMS and extracted PDMS. W-O-W.mp4 and O-W-O.mp4 are the movies of water-in-oil-in-water double emulsion generation and oil-in-water-in-oil double emulsion generation with blue food corloring dyes in water phase. The flow rate are kept at 30–50–500 ml per hr (inner phase–middle phase–outer phase). statistical analysis.pptx contains the pictures of generated double emulsion droplets for new chip and old chip associated with histogram in supplimentary S4 used for reproducibility analysis.