Research Data Leeds Repository
Data to support study of Spin States of Homochiral and Heterochiral Isomers of [Fe(PyBox)2]2+ Derivatives
Halcrow, Malcolm A and Burrows, Kay E and McGrath, Sarah E and Kulmaczewski, Rafał and Cespedes, Oscar and Barrett, Simon A (2017) Data to support study of Spin States of Homochiral and Heterochiral Isomers of [Fe(PyBox)2]2+ Derivatives. University of Leeds. [Dataset] https://doi.org/10.5518/184
Dataset description
Homochiral [Fe((R)-LPh)2]2+ (LPh = 2,6-bis{4-phenyloxazolinyl}pyridine) undergoes spin-crossover in CD3CN at 34 K lower temperature than its heterochiral diastereomer [Fe((R)-LPh)((S)-LPh)]2+.
Keywords: | iron; spin-crossover; isomers; chirality | ||||||
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Subjects: | F000 - Physical sciences > F100 - Chemistry | ||||||
Divisions: | Faculty of Engineering and Physical Sciences > School of Chemistry Faculty of Engineering and Physical Sciences > School of Physics and Astronomy |
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License: | Creative Commons Attribution 4.0 International (CC BY 4.0) | ||||||
Date deposited: | 11 Apr 2017 15:40 | ||||||
URI: | http://archive.researchdata.leeds.ac.uk/id/eprint/139 | ||||||