Research Data Leeds Repository

Data to support study of Spin States of Homochiral and Heterochiral Isomers of [Fe(PyBox)2]2+ Derivatives

Halcrow, Malcolm A and Burrows, Kay E and McGrath, Sarah E and Kulmaczewski, Rafał and Cespedes, Oscar and Barrett, Simon A (2017) Data to support study of Spin States of Homochiral and Heterochiral Isomers of [Fe(PyBox)2]2+ Derivatives. University of Leeds. [Dataset] https://doi.org/10.5518/184

Dataset description

Homochiral [Fe((R)-LPh)2]2+ (LPh = 2,6-bis{4-phenyloxazolinyl}pyridine) undergoes spin-crossover in CD3CN at 34 K lower temperature than its heterochiral diastereomer [Fe((R)-LPh)((S)-LPh)]2+.

Keywords: iron; spin-crossover; isomers; chirality
Subjects: F000 - Physical sciences > F100 - Chemistry
Divisions: Faculty of Mathematics and Physical Sciences > School of Chemistry
Faculty of Mathematics and Physical Sciences > School of Physics and Astronomy
Related resources:
LocationType
https://doi.org/10.1002/chem.201700820Publication
http://eprints.whiterose.ac.uk/114618/Publication
License: Creative Commons Attribution 4.0 International (CC BY 4.0)
Date deposited: 11 Apr 2017 15:40
URI: https://archive.researchdata.leeds.ac.uk/id/eprint/139

Files

Documentation

Data

Research Data Leeds Repository is powered by EPrints
Copyright © 2021 University of Leeds