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Data to support study of Spin States of Homochiral and Heterochiral Isomers of [Fe(PyBox)2]2+ Derivatives

Citation

Halcrow, Malcolm A. and Burrows, Kay E. and McGrath, Sarah E. and Kulmaczewski, Rafał and Cespedes, Oscar and Barrett, Simon A. (2017) Data to support study of Spin States of Homochiral and Heterochiral Isomers of [Fe(PyBox)2]2+ Derivatives. University of Leeds. [Dataset] https://doi.org/10.5518/184

Dataset description

Homochiral [Fe((R)-LPh)2]2+ (LPh = 2,6-bis{4-phenyloxazolinyl}pyridine) undergoes spin-crossover in CD3CN at 34 K lower temperature than its heterochiral diastereomer [Fe((R)-LPh)((S)-LPh)]2+.

Keywords: iron; spin-crossover; isomers; chirality
Subjects: F000 - Physical sciences > F100 - Chemistry
Divisions: Faculty of Engineering and Physical Sciences > School of Chemistry
Faculty of Engineering and Physical Sciences > School of Physics and Astronomy
Related resources:
LocationType
https://doi.org/10.1002/chem.201700820Publication
https://eprints.whiterose.ac.uk/114618/Publication
License: Creative Commons Attribution 4.0 International (CC BY 4.0)
Date deposited: 11 Apr 2017 15:40
URI: https://archive.researchdata.leeds.ac.uk/id/eprint/139

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