Research Data Leeds Repository
Data to support study of Spin States of Homochiral and Heterochiral Isomers of [Fe(PyBox)2]2+ Derivatives
Citation
Halcrow, Malcolm A. and Burrows, Kay E. and McGrath, Sarah E. and Kulmaczewski, Rafał and Cespedes, Oscar and Barrett, Simon A. (2017) Data to support study of Spin States of Homochiral and Heterochiral Isomers of [Fe(PyBox)2]2+ Derivatives. University of Leeds. [Dataset] https://doi.org/10.5518/184
Dataset description
Homochiral [Fe((R)-LPh)2]2+ (LPh = 2,6-bis{4-phenyloxazolinyl}pyridine) undergoes spin-crossover in CD3CN at 34 K lower temperature than its heterochiral diastereomer [Fe((R)-LPh)((S)-LPh)]2+.
Keywords: | iron; spin-crossover; isomers; chirality | ||||||
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Subjects: | F000 - Physical sciences > F100 - Chemistry | ||||||
Divisions: | Faculty of Engineering and Physical Sciences > School of Chemistry Faculty of Engineering and Physical Sciences > School of Physics and Astronomy |
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License: | Creative Commons Attribution 4.0 International (CC BY 4.0) | ||||||
Date deposited: | 11 Apr 2017 15:40 | ||||||
URI: | https://archive.researchdata.leeds.ac.uk/id/eprint/139 | ||||||