Research Data Leeds Repository

Data to support study of Gradual Thermal Spin-Crossover Mediated by a Re-Entrant Z’ = 1 to Z’ = 6 to Z’ = 1 Phase Transition.

Halcrow, Malcolm A and Kulmaczewski, Rafał and Cespedes, Oscar (2017) Data to support study of Gradual Thermal Spin-Crossover Mediated by a Re-Entrant Z’ = 1 to Z’ = 6 to Z’ = 1 Phase Transition. University of Leeds. [Dataset] https://doi.org/10.5518/164

Dataset description

An iron(II) complex shown exhibits gradual spin-crossover with T(1/2) approximately 208 K, and a weak discontinuity around 190 K which reflects a re-entrant symmetry breaking transition.

Keywords:	iron; spin-crossover; phase transition
Subjects:	F000 - Physical sciences > F100 - Chemistry
Divisions:	Faculty of Engineering and Physical Sciences > School of Chemistry
Related resources:	Location Type https://doi.org/10.1021/acs.inorgchem.7b00071 Publication http://eprints.whiterose.ac.uk/112952/ Publication
License:	Creative Commons Attribution 4.0 International (CC BY 4.0)
Date deposited:	28 Feb 2017 14:21
URI:	http://archive.researchdata.leeds.ac.uk/id/eprint/125
Additional details Additional details Creators: Creators ORCID Other ID Email Primary affiliation Primary affiliation ID Primary affiliation ID type Secondary affiliation Secondary affiliation ID Secondary affiliation ID type Halcrow, Malcolm A https://orcid.org/0000-0001-7491-9034 Kulmaczewski, Rafał https://orcid.org/0000-0002-3855-4530 Cespedes, Oscar https://orcid.org/0000-0002-5249-9523 Type of data: Dataset Research funders: EPSRC Grant numbers: EP/K012568/1, EP/K00512X/1 Publication date: 2017 Resource language: English Metadata language: English Research project title: Switchable molecular crystals, SQUID magnetometer Publisher: University of Leeds Contact Email Address: m.a.halcrow@leeds.ac.uk Last Modified: 03 Mar 2017 10:26

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Documentation

Compound naming and metadata [25kB] Compound naming and metadata [25kB] Compound naming and metadata [25kB] Visible to: Anyone File name: readme.pdf Content type: Documentation Mime-Type: application/pdf License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 25kB

Data

Single crystal X-ray diffraction [5MB] Single crystal X-ray diffraction [5MB] Single crystal X-ray diffraction [5MB] Visible to: Anyone File name: Crystal.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 5MB

Magnetic susceptibility [312kB] Magnetic susceptibility [312kB] Magnetic susceptibility [312kB] Visible to: Anyone File name: Magnetism.zip Content type: Data Mime-Type: application/zip License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 312kB

Mircroanalysis [262kB] Mircroanalysis [262kB] Mircroanalysis [262kB] Visible to: Anyone File name: Microanalysis.pdf Content type: Data Mime-Type: application/pdf License: Creative Commons Attribution 4.0 International (CC BY 4.0) File size: 262kB