Research Data Leeds Repository
Data to support Study of Ligand-Directed Metallation of a Gold Pyrazolate Cluster
Citation
Smith, Ryan A. and Kulmaczewski, Rafał and Halcrow, Malcolm A. (2023) Data to support Study of Ligand-Directed Metallation of a Gold Pyrazolate Cluster. University of Leeds. [Dataset] https://doi.org/10.5518/1361
Dataset description
Metallation of [Aun(L)n] (HL = 3-[pyrid-2-yl]-5-tertbutyl-1H-pyrazole; n = 3 or 4) with AgBF4 yields [Ag2Au4(L)4][BF4]2, where two edges of the Au4 square are spanned by Ag+ ions coordinated to its pendant pyridyl groups.
Keywords: | gold; silver; pyrazolate; metallophilic interactions; X-ray diffraction; fluorescence | ||||
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Divisions: | Faculty of Engineering and Physical Sciences > School of Chemistry | ||||
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License: | Creative Commons Attribution 4.0 International (CC BY 4.0) | ||||
Date deposited: | 08 Jun 2023 12:16 | ||||
URI: | https://archive.researchdata.leeds.ac.uk/id/eprint/1114 | ||||