Research Data Leeds Repository
Data to support study of Spin-Crossover in a New Iron(II)/Di(pyrazolyl)pyridine Complex with a Terpyridine Embrace Lattice
Citation
Michaels, Evridiki and Capel Berdiell, Izar and Vasili, Hari Babu and Pask, Christopher M. and Howard, Mark J. and Cespedes, Oscar and Halcrow, Malcolm A. (2022) Data to support study of Spin-Crossover in a New Iron(II)/Di(pyrazolyl)pyridine Complex with a Terpyridine Embrace Lattice. University of Leeds. [Dataset] https://doi.org/10.5518/1229
Dataset description
[FeL2]X2 ( L = 2,6-di{4-fluoropyrazol-1-yl}pyridine) exhibit hysteretic spin-transitions at T½ = 164 (X = BF4) and 148 K (X = ClO4). The perchlorate salt shows efficient TIESST below 120 K, and was characterized in its thermally trapped high-spin form, as well as in its thermodynamic high- and low-spin states.
Keywords: | iron; N-donor ligands; spin-crossover; spin state trapping; crystal engineering | ||||
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Subjects: | F000 - Physical sciences > F100 - Chemistry | ||||
Divisions: | Faculty of Engineering and Physical Sciences > School of Chemistry | ||||
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License: | Creative Commons Attribution 4.0 International (CC BY 4.0) | ||||
Date deposited: | 30 Sep 2022 14:22 | ||||
URI: | https://archive.researchdata.leeds.ac.uk/id/eprint/1028 | ||||