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Data to support study of Spin-Crossover in a New Iron(II)/Di(pyrazolyl)pyridine Complex with a Terpyridine Embrace Lattice

Citation

Michaels, Evridiki and Capel Berdiell, Izar and Vasili, Hari Babu and Pask, Christopher M. and Howard, Mark J. and Cespedes, Oscar and Halcrow, Malcolm A. (2022) Data to support study of Spin-Crossover in a New Iron(II)/Di(pyrazolyl)pyridine Complex with a Terpyridine Embrace Lattice. University of Leeds. [Dataset] https://doi.org/10.5518/1229

Dataset description

[FeL2]X2 ( L = 2,6-di{4-fluoropyrazol-1-yl}pyridine) exhibit hysteretic spin-transitions at T½ = 164 (X = BF4) and 148 K (X = ClO4). The perchlorate salt shows efficient TIESST below 120 K, and was characterized in its thermally trapped high-spin form, as well as in its thermodynamic high- and low-spin states.

Keywords: iron; N-donor ligands; spin-crossover; spin state trapping; crystal engineering
Subjects: F000 - Physical sciences > F100 - Chemistry
Divisions: Faculty of Engineering and Physical Sciences > School of Chemistry
Related resources:
LocationType
https://doi.org/10.1021/acs.cgd.2c00980Publication
https://eprints.whiterose.ac.uk/191436/Publication
License: Creative Commons Attribution 4.0 International (CC BY 4.0)
Date deposited: 30 Sep 2022 14:22
URI: https://archive.researchdata.leeds.ac.uk/id/eprint/1028

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