Research Data Leeds Repository

Data to support study of Supramolecular Iron Metallocubanes Exhibiting Site-Selective Thermal and Light-Induced Spin-Crossover

Citation

Halcrow, Malcolm A. and Capel Berdiell, Izar and Desplanches, Cédric and Hochdörffer, Tim and Kulmaczewski, Rafał and Wolny, Juliusz A. and Warriner, Stuart L. and Shahid, Namrah and Cespedes, Oscar and Schünemann, Volker (2019) Data to support study of Supramolecular Iron Metallocubanes Exhibiting Site-Selective Thermal and Light-Induced Spin-Crossover. University of Leeds. [Dataset] https://doi.org/10.5518/735¹

Dataset description

Two [{FeIII(OH2)6}Fe8(μ-L)12][BF4]7 cubane assemblies (L = a 4,6-pyrazolylpyrimid-2-one derivative) undergo spin-crossover selectively at just two opposite vertices of the cubane cages

Keywords:

iron; spin-crossover; supramolecular chemistry; X-ray crystallography; magnetic measurements

Subjects:

F000 - Physical sciences > F100 - Chemistry²

Divisions:

Faculty of Engineering and Physical Sciences > School of Chemistry³

Related resources:

Location	Type
https://doi.org/10.1021/jacs.9b08862⁴	Publication
https://eprints.whiterose.ac.uk/153161/⁵	Publication

License:

Creative Commons Attribution 4.0 International (CC BY 4.0)

Date deposited:

12 Nov 2019 10:03

URI:

https://archive.researchdata.leeds.ac.uk/id/eprint/602⁶

Additional details

Creators or authors:

Creators	ORCID	Primary affiliation	Primary affiliation ID	Primary affiliation ID type
Halcrow, Malcolm A.	https://orcid.org/0000-0001-7491-9034⁷	University of Leeds	https://ror.org/024mrxd33	ror
Capel Berdiell, Izar	https://orcid.org/0000-0003-3828-7097⁸	University of Leeds	https://ror.org/024mrxd33	ror
Desplanches, Cédric	https://orcid.org/0000-0001-8524-3690⁹	University of Bordeaux	https://ror.org/057qpr032	ror
Hochdörffer, Tim		Technical University of Kaiserslautern	https://ror.org/01qrts582	ror
Kulmaczewski, Rafał	https://orcid.org/0000-0002-3855-4530¹⁰	University of Leeds	https://ror.org/024mrxd33	ror
Wolny, Juliusz A.	https://orcid.org/0000-0002-2766-7492¹¹	Technical University of Kaiserslautern	https://ror.org/01qrts582	ror
Warriner, Stuart L.	https://orcid.org/0000-0002-7589-6011¹²	University of Leeds	https://ror.org/024mrxd33	ror
Shahid, Namrah	https://orcid.org/0000-0002-8090-7619¹³	University of Leeds	https://ror.org/024mrxd33	ror
Cespedes, Oscar	https://orcid.org/0000-0002-5249-9523¹⁴	University of Leeds	https://ror.org/024mrxd33	ror
Schünemann, Volker	https://orcid.org/0000-0002-3162-1032¹⁵	Technical University of Kaiserslautern	https://ror.org/01qrts582	ror

Type of data:

Dataset

Research funders:

EPSRC, EPSRC, Leverhulme Trust, EU COST, Diamond Light Source

Grant numbers:

EP/K012568/1, EP/K00512X/1, RPG-2015-095, CM1305, MT10334

Publication date:

2019

Resource language:

English

Metadata language:

English

Research project title:

Switchable molecular crystals, SQUID magnetometer, Exploiting a spin-crossover module, ECOSTBio

Publisher:

University of Leeds

Contact email:

m.a.halcrow@leeds.ac.uk¹⁶

Last Modified:

17 Dec 2024 15:13

Files

Documentation

compound naming and metadata [171kB]

¹⁷

compound naming and metadata [171kB]

¹⁹

Data

CHN microanalyses [854kB]

²¹

CHN microanalyses [854kB]

²³

Single crystal X-ray diffraction [10MB]

²⁵